Best place in Canada to get photography career?

I’ve read about photographers who walk into a company’s head quarters (like National Geographic) and after showing some samples of their work asked for a job. I am currently living in Montreal but I’m in a position to move to any part of Canada. I’m wondering where in Canada would offer the best chances at getting into a photography career.

It depends on the level of your photography and the job. Without knowing what you are qualified for there is no answer to your question.